This paper uses Monte Carlo technique, which is one of probabilistic methods of estimating the economical quantity of electric power generation in consideration of voltage stability in the aspect of power generation companies. In the power exchange system in Korea, when power generation companies participate in tenders for power generation capacity at the power exchange, they need to determine their power supply capacity considering the stability of electric power system. Thus, we purposed to propose an algorithm for estimating economical power generation capacity in theaspect of power generation companies, through which we can estimate the margin for voltage stability through P-V curve analysis by capacity according to the change of power generation capacity in a simulated system and to conduct Monte Carlo simulation in consideration of the margin