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DCA-MOD 법에 의한 High $J_c$ YBCO 박막의 제조
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  • DCA-MOD 법에 의한 High $J_c$ YBCO 박막의 제조
  • The Preparation of High $J_c$ YBCO Films by DCA-MOD Method
저자명
김병주,김혜진,이금영,이종범,김호진,이희균,홍계원,Kim. Byeong-Joo,Kim. Hye-Jin,Yi. Keum-Young,Lee. Jong-Beum,Kim. Ho-Jin,Lee. Hee-Gyoun,Hong. Gye-Won
간행물명
Progress in superconductivity
권/호정보
2006년|8권 1호|pp.59-64 (6 pages)
발행정보
한국초전도학회
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

High $J_c;YBa_2Cu_3O_x$ superconducting films were fabricated by MOD method using fluorine-free dichloroacetic acid(DCA) as chelating solvent for preparing precursor solution. Coating solutions were prepared by dissolving Y-, Ba- and Cu-acetates in DCA solvent followed by drying in rota vapor to obtain the blue gel that is diluted in methanol and 2-methoxyethanol for adjusting the cation concentration. DCA-MOD precursor solution was coated on a single crystal(001) $LaAlO_3(LAO)$ substrate by a dip coating method with a speed of 25 mm/min. Coated films were calcined at lower temperature up to $500^{circ}C$ in flowing oxygen atmosphere with a 7.2% humidity. Conversion heat treatment was performed at various temperatures of $780{sim}810^{circ}C$ for 2 h in flowing Ar gas containing 1000 ppm oxygen with a humidity of 9.45%. SEM observations showed that films have very dense microstructures for the films prepared at the temperature higher than $800^{circ}C$ regardless of diluting solvent; methanol or 2-methoxyethanol. X-ray diffraction analysis showed that YBCO grains grew with a (001) preferred orientation. A High critical current density($J_c$) of 1.28 $MA/cm^2$(@77 K and self-field) was obtained id. the YBCO film prepared using 2-methoxyethanol as a solvent.