The electrical resistivity prospecting method with dipole-dipole array was applied to the Mooreung landfill site in order to survey the existence of leachate around the landfill site. Moreover, if there is leachate within Mooreung landfill site, the analysis of potential pathways to exterior environments was tried. Within the landfill site, the over-all characteristics of the electrical resistivity anomalies suggest that the leachate induced from the landfill materials has infiltrated the basement rock and fill the pores of basement rock in some parts of the landfill site. The consistency of the anomaly locations (left part of each survey line), anomaly geometries, and absolute resistivity value of anomaly through the 3 survey lines suggests that the resistivity anomaly be connected from the upstream to the downstream and correspond to the leachate material. Finally, the result from the electrical resistivity survey line near the gateway of the landfill site suggests that some of the leachate induced from landfill material leaks to the exterior groundwater system. It is necessary that more surveys using both geochemical and geophysical methods should be performed to find out potential pathways and depths of the leachate more precisely.