This paper deals with the application of the numerical differentiation in the structural analyses. Derivative values of the geometry of structure are definitely needed for analysing the structural behavior. In this study, free vibration problems of arches are chosen for verifying the numerical differential technique in the structural analyses. The curvature parameters composed with the derivatives of arch geometry obtained herein are quite agreed with those of analytical method. Also, natural frequencies with curvature parameters obtained by using the forward fifth polynomial method are quite agreed with those in the literature. The numerical differentiation technique can be practically utilized in the structural analyses.