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Structure and Property Modification of Bimodal Molecular Weight Distribution Polyethylene by Electron Beam Irradiation
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  • Structure and Property Modification of Bimodal Molecular Weight Distribution Polyethylene by Electron Beam Irradiation
  • Structure and Property Modification of Bimodal Molecular Weight Distribution Polyethylene by Electron Beam Irradiation
저자명
Lee. Sang-Man,Jeon. Hye-Jin,Choi. Sun-Woong,Song. Hyun-Hoon,Nho. Young-Chang,Cho. Kyu-Cheol
간행물명
Macromolecular research
권/호정보
2006년|14권 6호|pp.640-645 (6 pages)
발행정보
한국고분자학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Polyethylene of bimodal molecular weight distribution was irradiated with an electron beam. The thermal and mechanical properties were examined by DSC, small and wide angle X-ray scattering and static tensile test according to the crystal morphology of the irradiated samples. The crystal morphology change upon irradiation, as revealed by wide angle X-ray scattering, correlated well with the changes in melting enthalpy, whereas the lamellar thickness and the amorphous gap thickness remained virtually unchanged at irradiation doses up to 500 kGy. Crosslinks in the crystal domains became evident at an energy level of 250 kGy, resulting in reduced crystallinity and crystal size of the (110) and (200) planes. The samples became stiff and brittle with increased irradiation dose, which seem to be more relevant to the amount of cross links than the crystal morphology changes.