By measuring concrete temperature and strains of concrete and reinforcing bars throughout gages embedded and also by observing the crack occurrence, this study aims at the characteristics of structural behavior of subway wall structure in associate with concrete ages. The length of 23.5m, thickness of 2.0m of real subway custody line was selected as a representative structure and 7 thermocouples and 6 strain gages were installed to measure the behavior of wall structure. The results were compared and verified with analytical results using MIDAS in order to show their usefulness. It was found that only attachment of strain gages on the surface of reinforcing bars can figure out the timing of crack occurrence and hydration heat program is useful to estimate comparatively exact magnitudes of temperature. Since estimated time of crack occurrence throughout thermal stress analysis depends on the period of transferred thermal stress from concrete to reinforcing bars, however, cracks from naked eyes were identified later than analytical results. Cracks were observed first at the center of wall line and then to the end of line symmetrically.