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Synthesis and Characterization of Crosslinked Polyacrylates Containing Cubane and Silyl Groups
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  • Synthesis and Characterization of Crosslinked Polyacrylates Containing Cubane and Silyl Groups
  • Synthesis and Characterization of Crosslinked Polyacrylates Containing Cubane and Silyl Groups
저자명
Mahkam. Mehrdad,Assadi. Mohammad,Mohammadzadeh. Rana
간행물명
Macromolecular research
권/호정보
2006년|14권 1호|pp.34-37 (4 pages)
발행정보
한국고분자학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Attaching the organosilyl groups to macromolecular chains of 2-hydroxyethyl methacrylate (HEMA) should lead to important modifications of polymer properties. t-$BuMe_{2}Si$ and cubane-l, 4-dicarboxylic acid (CDA) were covalently linked with 2-hydroxyethyl methacrylate (HEMA). The silyl-linked HEMA is abbreviated as TSMA, while cubane-l ,4-dicarboxylic acid (CDA) linked to two HEMA groups is the cross-linking agent (CA). Free radical cross-linking copolymerization of TSMA and HEMA with various ratios of CA as the cross-linking agent was carried out at 60-70$^{circ}C$. The compositions of the cross-linked, three-dimensional polymers were determined by FTIR spectroscopy. The glass transition temperature ($T_{g}$) of the network polymers was determined calorimetrically. The $T_{g}$ of the network polymer increased with increasing cross-linking degree.