This study has been conducted to quantify the emissions of Volatile Organic Compounds (VOCs) in a conference room. The carpet has emitted a variety of VOCs, but in this study, 2 VOCs compounds have been considered: Ethylbenzene and 1, 2, 3-Trimethylbenzene. In this study, a three dimensional numerical analysis has been carried out to investigate the emission and behavior characteristics of Ethylbenzene and 1, 2, 3-Trimethylbenzene emitted from the carpet in the conference room. The mass diffusion coefficient and the initial concentrations of VOCs in the carpet have been obtained from experimental data with non-linear regression. It has been found that the concentrations and emission factors of VOCs have exponentially decayed with time and that the concentration gradients and emission factors of VOCs are different from each other for various components. This study may supply fundamental understandings for the emission and behavior characteristics of VOCs.