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Recovery of Cobalt in Sulfuric Acid Leaching Solution Using Oxalic Acid
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  • Recovery of Cobalt in Sulfuric Acid Leaching Solution Using Oxalic Acid
  • Recovery of Cobalt in Sulfuric Acid Leaching Solution Using Oxalic Acid
저자명
Sohn. Jeong-Soo,Yang. Dong-Hyo,Shin. Shun-Myung,Kang. Jin-Gu
간행물명
Geosystem engineering
권/호정보
2006년|9권 3호|pp.81-86 (6 pages)
발행정보
한국암반공학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Oxalic acid was used for recovering cobalt from leaching solution of spent lithium ion battery by precipitation method. Crushed powders containing $LiCoO_2$ of spent lithium ion battery were obtained by crushing, magnetic separation and screening process. These powders were dissolved in 2 M $H_2SO_4$ solution with $H_2O_2$ as a reducing agent. After dissolving Co and Li components, the solution of oxalic acid was added. Co(II) in leaching solution could be removed in the form of insoluble oxalates. The precipitate formed was crystalline, compact and easily filtered. With the increase in oxalic acid, the rate of cobalt precipitate increased to 90% at 1:4 mole ratio of Co(II) and oxalic acid concentration. When cobalt ion was precipitated into cobalt oxalate, nickel and copper ions were co-precipitated but there were no co-precipitates of Li, Al and Fe. The amounts of Ni and Cu in the solutions were below 1%. After heat treatment of precipitates at above $250^{circ}C$, cobalt oxalate was changed into cobalt oxide.