Recently emission regulation on diesel vehicles is getting stringent and research on aftertreatment technology such as DPF and DOC has been carried out actively. Even though PM(Particulate matters) reduction efficiency in DOC is relatively low but the structure is simpler and very effective in the reduction of gas materials and unregulated materials. Therefore it has been applied to smaller diesel vehicles. The aims of this research is to investigate the emission reduction characteristics of DOC; DOC performance of regulated and unregulated material emission reduction. It results a Pt based catalyst demonstrated higher emission reduction efficiency than a Pt-V based catalyst in CVS-75 mode, and also the reduction efficiency of unidentified material was excellent.