- 희토류 첨가 광소재의 나노구조 : Dy 첨가 Ge-As-S 유리의 X-선 흡수 스펙트럼 분석
- ㆍ 저자명
- 최용규,송재혁,신용범,허종,Choi. Yong-Gyu,Song. Jay-Hyok,Shin. Yong-Beom,Heo. Jong
- ㆍ 간행물명
- 한국세라믹학회지
- ㆍ 권/호정보
- 2006년|43권 3호|pp.177-184 (8 pages)
- ㆍ 발행정보
- 한국세라믹학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
Dy $L_3$-edge XANES and EXAFS spectra of chalcogenide Ge-As-S glass doped with ca. 0.2 wt% dysprosium have been investigated along with some reference Dy-containing crystals. Amplitude of the white-line peak in XANES spectrum of the glass sample turns out to be stronger than that of other reference crystals, i.e., $DY_2S_3,;Dy_2O_3;and;DyBr_3$. It has been verified from the Dy $L_3$-edge EXAFS spectra that a central Dy atom is surrounded by $6.7{pm}0.5$ sulfur atoms in its first coordination shell in the Ge-As-S glass, which is relatively smaller than 7.5 of the $Dy_2S_3$ crystal. Averaged Dy-S inter-atomic-distance of the glass ($2.78{pm}0.01{AA}$) also turns out to be somewhat shorter than that of the $Dy_2S_3$ crystal ($2.82{pm}0.01{AA}$). Such nanostructural changes occurring at Dy atoms imply there being stronger covalency of Dy-S chemical bonds in the Ge-As-S glass than in the crystal counterpart. The enhanced covalency in the nanostructural environment of $Dy^{3+}$ ions inside the glass would then be responsible for optical characteristics of the $4f{leftrightarrow}4f$ transitions of the dopants, i.e., increase of oscillator strengths and spontaneous radiative transition probabilities.