Around Yeongsan river basin, there are Yeongkwang Gundong, Muan Inpyeong Tombs, Muu Gusan-ri Tombs and Hampyeong Guksan remain from which a lot of iron artifacts were excavated. Among them, 6 iron artifacts were chosen, and their microstructures were analyzed. As a result, Iron artifacts were produced sponge iron by the low temperature reduction process and a part of microstructure have the possibility that steel made by decarburizing. And also, by tempering the parts which need high strength, the iron artifacts had high strength and by distributing the weakness of the tempered structure to the nearby untempered parts, their breaking was prevented and they had the durability. These skills were used then. Especially these skills were found to be used in the 2nd century by high skilled people because an iron axe excavated at Yeongkwang Gundong of 2nd century by the historical record showed that the skill was used. Also microstructures were found to show the possibility that the iron technology was inherited to the late 5th century. When producing iron artifacts made of sponge iron containing small amount of carbon, that was made by the production process repeating molding, carburizing, heat treatment and hammering.