We observed the application possibility of inductive coupler for the underground high-voltage power line communication by means of analysis of signal transmission characteristics and magnetic properties on annealing temperatures for high-permeability Fe-base amorphous alloys. The best electromagnetic and transmission characteristics were shown in nano-crystalline precipitated alloy annealed at temperature $510^{circ}C$. The transmission characteristics in the low-frequency band depend on permeability of magnetic core materials and its properties of high-frequency band can be improved by impedance matching. Using the high pass filter embedded in the coupler, other noise signal band except for communication signals could be cut off.