In this study, performance of 2 pure hydrocarbons and 7 mixtures was measured in an attempt to substitute HCFC22 used in air-conditioners and heat pumps. The mixtures were composed of R1270 (propylene), R290 (propane), HFC152a, and RE170 (Dimethyl ether, DME). The pure and mixed refrigerants tested have GWPs of $3{sim}58$ as compared to that of $CO_2$ and the mixtures are all near-azeotropic showing the gliding temperature difference (GTD) of less than $0.6^{circ}C$. Thermodynamic cycle analysis was carried out to determine the optimum compositions and actual tests were performed in a laboratory heat pump test bench at the evaporation and condensation temperatures of 7.5 and $45.1^{circ}C$ respectively. Test results show that the coefficient of performance (COP) of these mixtures is up to 5.7% higher than that of HCFC22. While propane showed 11.5% reduction in capacity, most of the fluids tested had the similar capacity to that of HCFC22. Compressor discharge temperatures were reduced by $11{sim}17^{circ}C$ with these fluids. There was no problem with mineral oil since the mixtures were mainly composed of hydrocarbons. The amount of charge was reduced up to 55% as compared to HCFC22. Overall, these fluids provide good performance with reasonable energy savings without any environmental problem and thus can be used as long term alternatives for. residential air-conditioning and heat pumping application.