During the SI engine starting up, starting conditions directly contribute to the harmful emissions in spark ignition engines. The effects of catalyst temperatures and fuel injection skip methods on HC emissions were investigated. The test was conducted on a 1.5L, 4-cylinder, 16 valve, multipoint-port-fuel-injection gasoline engine. To understand the formation of HC emissions, HC concentration was measured in an exhaust port using a Fast Response Flame Ionization Detector(FRFID). The result showed that HC emissions, which were generated during initial stage of the starting, could be reduced by coolant temperature and fuel injection skips. And through the vehicle test of ECE15+EUDC, it is convinced that the optimized fuel injection skip method according to coolant temperatures have favourable effects on the reduction of harmful exhaust emissions including HC during the SI engine start.