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  • Katayama Equation Modified on the Basis of Critical-Scaling Theory
저자명
임경희,Lim. Kyung-Hee
간행물명
한국유화학회지
권/호정보
2006년|23권 3호|pp.185-191 (7 pages)
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한국유화학회
파일정보
정기간행물|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

It is desirable to have an accurate expression on the temperature dependence of surface(or interfacial) tension ${sigma}$, because most of the interfacial thermodynamic functions can be derived from it. There have been proposed several equations on the temperature dependence of the surface tension, ${sigma}(T)$. Among them $E{ddot{o}}tv{ddot{o}}s$ equation and the one modified by Katayama, which is called Katayama equation, for improving accuracies of $E{ddot{o}}tv{ddot{o}}s$ equation close to critical points, have been most well-known. In this article Katayama equation is interpreted on the basis of the cell model to understand the nature of the equation. The cell model results in an expression very similar to Katayama equation. This implies that, although $E{ddot{o}}tv{ddot{o}}s$ and Katayama equations were obtained on the basis of experimental results, they have a sound theoretical background. The Katayama equation is also modified with the phase volume replaced with a critical scaling expression. The modified Katayama equation becomes a power-law equation with the exponent slightly different from the value obtained by critical-scaling theory. This implies that Katayama equation can be replaced by a critical-scaling equation which is proven to be accurate.