The Air Quality Sensor(AQS), located near the fresh air inlet, serves to reduce the amount of pollution entering the vehicle cabin through the HVAC(heating, ventilating, and air conditioning) system by sending a signal to close the fresh air inlet door/ventilation flap when the vehicle enters a high pollution area. The sensor module which includes two independent sensing elements for responding to diesel and gasoline exhaust gases, and temperature sensor and humidity sensor was designed for intelligent AQS in automobile. With this sensor module, AVR microcontroller was designed with back propagation neural network to a powerful gas/vapor pattern recognition when the motor vehicles pass a pollution area. Momentum back propagation algorithm was used in this study instead of normal backpropagation to reduce the teaming time of neural network. The signal from neural network was modified to control the inlet of automobile and display the result or alarm the situation in this study. One chip microcontroller, ATmega 128L(ATmega Ltd., USA) was used for the control and display. And our developed system can intelligently reduce the malfunction of AQS from the dampness of air or dense fog with the backpropagation neural network and the input sensor module with four sensing elements such as reducing gas sensing element, oxidizing gas sensing element, temperature sensing element and humidity sensing element.