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Kinetic Features of the Cobalt Dihalide/Methylaluminoxane Catalytic System in 1,3-Butadiene Polymerization
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  • Kinetic Features of the Cobalt Dihalide/Methylaluminoxane Catalytic System in 1,3-Butadiene Polymerization
  • Kinetic Features of the Cobalt Dihalide/Methylaluminoxane Catalytic System in 1,3-Butadiene Polymerization
저자명
Nath. Dilip Chandra Deb,Fellows. Christopher M.,Shiono. Takeshi
간행물명
Macromolecular research
권/호정보
2006년|14권 3호|pp.338-342 (5 pages)
발행정보
한국고분자학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The kinetic features of polymerization with an active site comprising cobalt dihalides ($CoX_2$, where X=Cl, Br, I) activated by methylaluminoxane (MAO) were investigated in 1,3-butadiene polymerization. The catalytic system exhibited the characteristic features of living polymerization. The initiation ($k_i$) and propagation ($k_p$) rate coefficients were estimated using the kinetic model for slow initiation previously reported by Shiono et al. The energy of activation fur the propagation reaction was calculated to be 27-30 $kJmol^{-1}$. The marked changes in reaction rate observed with different halides could be adequately described in terms of variations in the initiation process, with the same Arrhenius curve fitting propagation rate coeffcients estimated from all three halides, suggesting that the halide does not participate in the growing chain end.