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High-pressure rheology of polymer melts containing supercritical carbon dioxide
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  • High-pressure rheology of polymer melts containing supercritical carbon dioxide
  • High-pressure rheology of polymer melts containing supercritical carbon dioxide
저자명
Lee. Sang-Myung,Han. Jae-Ro,Kim. Kyung-Yl,Ahn. Young-Joon,Lee. Jae-Wook
간행물명
Korea-Australia rheology journal
권/호정보
2006년|18권 2호|pp.83-90 (8 pages)
발행정보
한국유변학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Supercritical carbon dioxide ($scCO_2$) has advantages of being incorporated in polymer with high solubility and of being recovered easily by depressurizing. $scCO_2$ reduces the viscosity of polymer melt and it is expected to be use as a plasticizing agent. In this work, we studied on the effect of $scCO_2$ on the rheological properties of polymer melts during extrusion process. Slit die attached to twin screw extruder was used to measure the viscosity of polymer melts plasticized by supercritical $CO_2$. A gas injection system was devised to accurately meter the supercritical $CO_2$ into the extruder barrel. Measurements of pressure drop within the die, confirmed the presence of a one phase mixture and a fully developed flow during the measurements. The viscosity measurement of polypropylene was performed at experimental conditions of various temperatures, pressures and $CO_2$ concentrations. We observed that melt viscosity of polymer was dramatically reduced by $CO_2$ addition.