The coal gasification fuel is important to replace petroleum fuel. Also they have many benefits for reducing the air pollution. Measurements on the combustion characteristics of synthetic gas from coal gasification have been conducted as compared with LPG in constant volume combustion chamber. The fuel is low caloric synthetic gas containing carbon monoxide 30%, hydrogen 20%, carbon dioxide 5%, and nitrogen 45%. To elucidate the combustion characteristics of the coal gasification fuel, the combustion pressures, combustion durations, and pollutants(NOx, $CO_2$, CO) are measured with equivalence ratios($phi$), and initial pressures of fuel-air mixture in constant volume chamber. In the case of the coal gasification fuel, maximum combustion pressure and NOx concentration are lower rather than LPG fuel. However CO and $CO_2$ emission concentration are similar to that of LPG fuel.