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Segmental Motions and Associated Dynamic Mechanical Thermal Properties of a Series of Copolymers Based on Poly(hexamethylene terephthalate) and Poly(1,4-cyclohexylenedimethylene terephthalate)
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  • Segmental Motions and Associated Dynamic Mechanical Thermal Properties of a Series of Copolymers Based on Poly(hexamethylene terephthalate) and Poly(1,4-cyclohexylenedimethylene terephthalate)
저자명
Jeong. Young-Gyu,Lee. Sang-Cheol,Jo. Won-Ho
간행물명
Macromolecular research
권/호정보
2006년|14권 4호|pp.416-423 (8 pages)
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한국고분자학회
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The dynamic mechanical thermal properties of poly(hexamethylene terephthalate) (PHT), poly(1,4-cyclohexylenedimethylene terephthalate) (PCT) and their P(HT-co-CT) random copolymers in the amorphous state were examined as a function of temperature and frequency. All the samples exhibited two main relaxation processes in the plot of tan ${delta}$ versus temperature: the primary ${alpha}$-relaxation associated with the glass transition and the secondary ${eta}$-relaxation attributed to the local segmental motions of mostly cyclohexylene rings for PCT and to cooperative motions of methylene, carboxyl, and phenylene groups for PHT. Both ${alpha}$- and ${eta}$-relaxation temperatures increased with increasing CT content. The activation energy of the ${alpha}$-relaxation increased with increasing CT content, whereas that of the ${eta}$-relaxation decreased. The sub-glassy secondary ${eta}$-relaxation processes of PCT and PHT were investigated in terms of the cooperativity of main-chain segmental motions.