Viscose rayon has advantages such as vivid luster, good dyeability, low static electricity, good absorbance and good spinnability but also has flaws such as easy crease and decrease of physical properties when it gets wetting, and it requires dry cleaning. Therefore in order to synthesize the polymer to solve the problems of rayon while keeping the advantages of it, this study made the high specific gravity polyester for ultra drape property and high contraction polyester for rayon-like fiber having volume, soft and warm sense. The polyester with high specific gravity, 1.47 was made by adding 7 wt% of $BaSO_4$ as additive. High contraction polyester was made by copolymerization by using IPA 5 mole% to increase the amorphous region as comonomer and also using Newpol BPE-20(NPE) 1.5 wt% not to decrease the properties.