In order to prepare neat barium titanate/silica ($BaTiO_3/SiO_2$) composite fibers, combined process of sol-gel synthesis and electrospinning was utilized. Electrospun composite fibers were subjected to the high temperature calcinations to fabricate the crystalline structure of $BaTiO_3$. The fraction of barium titanate to silica in fiber and the calcination temperature of fiber were varied. Prepared $BaTiO_3/SiO_2$ composite fibers have diameters of 500 nm to $3;{mu}m$ and show the neat surface morphology without any porous structure. Calcined composites fibers were characterized using powder X-ray diffraction (XRD), scanning electron microscopy (SEM), and Fourier transform infrared spectroscopy (FT-IR).