Spray combustion characteristics of the conducting fuel electrospray has been studied for clean combustion technology. The electrospraying multiplexed system which can maintain the characteristics of the cone-jet mode is able to obtain charged micro droplets with high flow rate. In addition, they have monodisperse distribution during operating the electrospray in the cone-jet mode. The multiplexed grooved nozzle system with the extractor was applied to this experimental device set up. The stable grooved mode can be generated by the grooved nozzle and this electrospray system was applied to the diffusion combustion. It is the first step to discover the diffusion combustion characteristics of the electrospray, In case of the single grooved nozzle electrospray the diffusion flames are occurred at each Jet of grooved mode and they are quite stable. The exhaust gas analysis was indicated that there is the critical point which can make very stable diffusion combustion