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Effect of shear on poly(styrene-b-isoprene) copolymer micelles
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  • Effect of shear on poly(styrene-b-isoprene) copolymer micelles
  • Effect of shear on poly(styrene-b-isoprene) copolymer micelles
저자명
Bang. Joon-A,Lodge. Timothy P.
간행물명
Korea-Australia rheology journal
권/호정보
2007년|19권 4호|pp.227-232 (6 pages)
발행정보
한국유변학회
파일정보
정기간행물|ENG|
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기타
이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The use of various shearing apparatuses to study the phase behavior of poly(styrene-b-isoprene) diblock copolymer micelles is described. A DMTA rheometer was modified so that one can apply oscillatory shear and obtain the scattering pattern along the shear gradient direction. A cone and plate shear cell was designed to access scattering along the shear vorticity direction, and both oscillatory and steady shear can be applied. The most popular way to employ steady shear on relatively low viscosity fluids is to use a Couette cell, because a high shear rate can be readily achieved without disturbing the sample by overflow. In this work, oscillatory shear was used to obtain a single crystal-like scattering pattern, and thereby to examine the mechanism of the thermotropic transition between face-centered cubic (fcc) and body-centered cubic (bcc) lattices. By applying the steady shear, the response of the fcc lattices to various shear rates is discussed.