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LSGM계 음극지지형 고체산화물 연료전지에 적용된 LDC 완충층의 효과
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  • LSGM계 음극지지형 고체산화물 연료전지에 적용된 LDC 완충층의 효과
저자명
송은화,정태주,김혜령,손지원,김병국,이종호,이해원,Song. Eun-Hwa,Chung. Tai-Joo,Kim. Hae-Ryoung,Son. Ji-Won,Kim. Byung-Kook,Lee. Jong-Ho,Lee. Hae-Weon
간행물명
한국세라믹학회지
권/호정보
2007년|44권 12호|pp.710-714 (5 pages)
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한국세라믹학회
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

LSGM$(La_{0.8}Sr_{0.2}Ga_{0.8}Mg_{0.2}O_{3-{delta}})$ is the very promising electrolyte material for lower-temperature operation of SOFCs, especially when realized in anode-supported cells. But it is notorious for reacting with other cell components and resulting in the highly resistive reaction phases detrimental to cell performance. LDC$(La_{0.4}Ce_{0.6}O_{1.8})$, which is known to keep the interfacial stability between LSGM electrolyte and anode, was adopted in the anode-supported cell, and its effect on the interfacial reactivity and electrochemical performance of the cell was investigated. No severe interfacial reaction and corresponding resistive secondary phase was found in the cell with LDC buffer layer, and this is due to its ability to sustain the La chemical potential in LSGM. The cell exhibited the open circuit voltage of 0.64V, the maximum power density of 223 $mW/cm^2$, and the ohmic resistance of $0.17{Omega}cm^2$ at $700^{circ}C$. These values were much improved compared with those from the cell without any buffer layer, which implies that formation of the resistive reaction phases in LSGM and then deterioration of the cell performance is resulted mainly from the La diffusion from LSGM electrolyte to anode.