As the web document of XML, an exchange language of data in the advanced Internet, is increasing, a target of information retrieval becomes the web documents. Therefore, there we researches on structure, integration and retrieval of XML documents. This paper proposes a clustering method of XML documents based on frequent structures, as a basic research to efficiently process query and retrieval. To do so, first, trees representing XML documents are decomposed and we extract frequent structures from them. Second, we perform clustering considering the weight of large items to adjust cluster creation and cluster cohesion, considering frequent structures as items of transactions. Third, we show the excellence of our method through some experiments which compare which the previous methods.