The paper discussed various techniques for islanding detection and described in detail the working principles of ROCOF and vector shift relays. A simulator was used to investigate why the stability of both types of relays maybe affected by network and load switching, short-circuit faults and in the case of a ROCOF relay the loss of bulk generation or the tripping of a transmission feeder. Finally, to enhance the reliability of Loss of Mains protection, a new islanding detection technique based on a GPS synchronized phasor measurement system was proposed.