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Poly(vinylidene fluoride)/Poly(ethylene-co-vinyl acetate) (20/80) Blend. I. Miscibility and Crystallization Behavior
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  • Poly(vinylidene fluoride)/Poly(ethylene-co-vinyl acetate) (20/80) Blend. I. Miscibility and Crystallization Behavior
  • Poly(vinylidene fluoride)/Poly(ethylene-co-vinyl acetate) (20/80) Blend. I. Miscibility and Crystallization Behavior
저자명
Lee. Jong-Soon,Kim. Kap-Jin
간행물명
Fibers and polymers
권/호정보
2007년|8권 3호|pp.237-242 (6 pages)
발행정보
한국섬유공학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The miscibility and crystallization behavior of the blends of poly(vinylidene fluoride) (PVDF) and ethylene/vinyl acetate(20/80) copolymer (EVAc80) have been studied using a differential scanning calorimeter and a polarizing microscope equipped with a heating stage. From the melting point depression, the values of interaction energy density B were calculated to be $-1.3004;(cal/cm^3)$ and the Flory-Huggins interaction parameter $X_{12}$ was found to be -0.0818 at 445.6K. With increasing concentration of EVAc80, the radial growth rate of spherulite was reduced drastically. The FT-IR analysis of samples quenched from the melt to various temperatures showed increasing content of ${eta}$-phase with increasing amount of blended EVA80 along with lower quenching temperature.