In this study, a new method of combustion characteristics have been proposed to reduce exhaust emissions in a diesel engine using four kinds of mixed fuel. Mixed fuels show four different torque ratios between diesel oil md natural gas, which are 4:0, 3:1, 2:2 and 1:3. In order to investigate the exhaust gas during combustion, exhaust gases are sampled by gas analyzer, for example NOx, Soot, CO, and HC, as the RPM changed. As a result, the NOx, CO, and HC concentrations of mixed fuel are higher than those of diesel oil only. However, the Soot concentration of mixed fuel is lower when diesel oil is burned.