Many techniques have been proposed for mapping from XML to relations, but most techniques did not negotiate the semantics of XML data. The semantics is important to validate storage, query optimization, modification anomaly in process of schema design. Specially, functional dependencies are an important part of database theory, also it is basis of normalization for relational table in BCNF. This paper propose a new technique that reflect functional dependencies to store relation mapped from XML based on XML Schema. The technique can reduce storage redundancy and can keep up content and structure with constraint described by functional dependencies.