- 고용량 양극재료 개발을 위한 $LiNi_{1-y-z}(M_1)_y(M_2)_zO_2$의 합성과 전기화학적 특성
- ㆍ 저자명
- 송명엽,Song. Myoung-Youp
- ㆍ 간행물명
- 한국수소 및 신에너지학회 논문집
- ㆍ 권/호정보
- 2007년|18권 3호|pp.325-333 (9 pages)
- ㆍ 발행정보
- 한국수소및신에너지학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
[ $LiNi_{0.995}Al_{0.005}O_2$ ], $LiNi_{0.990}Ti_{0.010}O_2$ and $LiNi_{0.0990}Al_{0.005}Ti_{0.005}O_2$ were synthesized with a combustion method by calcining in an $O_2$ stream at $750^{circ}C$ for 36 h. The X-ray diffraction patterns of these synthesized samples showed $-NaFeO_2$ structure of rhombohedral system(space group; $R{ar{3}};m$) with no evidence of impurities. Among these samples, $LiNi_{0.995}Al_{0.005}O_2$ exhibited comparatively high first discharge capacity and discharge capacity, and the best cycling performance. $LiNi_{0.995}Al_{0.005}O_2$ had the first discharge capacity of 165.2 mA h/g and a discharge capacity of 116.7 mA h/g at the 50th cycle at 0.1C rate. It showed the first discharge capacity of 141.0 mA h/g and a discharge capacity of 93.5 mA h/g at the 50th cycle at 0.5C rate.