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염화에텐류 화합물 및 전자공여체가 VC 탈염소화 속도에 미치는 영향
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  • 염화에텐류 화합물 및 전자공여체가 VC 탈염소화 속도에 미치는 영향
  • The Effect of Chlorinated Ethenes and Electron Donor on VC Dehalogenation Rate
저자명
배재호,이일수,박영구,Bae. Jae-Ho,Lee. Il-Su,Park. Young-Koo
간행물명
한국유화학회지
권/호정보
2007년|24권 4호|pp.436-443 (8 pages)
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한국유화학회
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정기간행물|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Anaerobic reductive dehalogenation of perchloroethene (PCE) was studied with lactate as the electron donor in a continuously stirred tank reactor (CSTR) inoculated with a mixed culture previously shown to dehalogenate vinyl chloride (VC). cis-1,2- dichloroethene (cDCE) was the dominant intermediate at relatively long cell retention times (>56 days) and the electron acceptor to electron donor molar ratio (PCE:lactate) of 1:2. cDCE was transformed to VC completely at the PCE to lactate molar ratio of 1:4, and the final products of PCE dehalogenation were VC (80%) and ethene (20%). VC dehalogenation was inhibited by cDCE dehalogenation. Propionate produced from the fermentation of lactate might be used as electron donor for the dehalogenation. Batch experiments were performed to evaluate the effects of increased hydrogen, VC, and trichloroethene (TCE) on VC dehalogenation which is the rate-limiting step in PCE dehalogenation The addition of TCE increased the VC dehalogenaiton rate more than an increase in the $H_2$ concentration, which suggests that the introduction of TCE induces the production of an enzyme that can comtabolize VC.