In this paper, we propose a simple scheme which produces a new S-box from a given S-box. We use well-known conversion technique between the polynomial functions over a finite field $F_{2^n}$ and the boolean functions from $F_2^n$ to $F_2$. We have applied this scheme to Rijndael S-box and obtained 29 new S-boxes, whose linear complexities are improved. We investigate their cryptographic properties via transform domain analysis.