This study was performed to compare the load-carrying capacities of the reinforced concrete structure between the carbon fiber adhesion reinforcement method and the external post-tensioning method and further estimate the effective stress of the reinforced material by analyzing the experimental reinforcing effect of each method and the behavior resulting from each method. As a result, it was found out that the effective stress of the carbon fiber reinforcement according to the carbon fiber adhesion reinforcement method had an unexpected value, and also, bearing of the stress was found to be far from sharing thereof. That is to say, while the carbon fiber was bearing the whole stress to some limits, it got to be momentarily ruptured as soon as it went beyond such limits. On the other hand, the external post-tensioning method has the advantage of inducing an initial effective stress by introducing a strain, and thus, it was found that behavior or bearing of the stress was also found to be a solid behavior of the steel wire. This method was also found to be more efficient and excellent than the carbon fiber adhesion reinforcement method in the reinforcing effect or securing the effective stress. Accordingly, we were to discuss the effective stress as comparatively examined, focusing on deriving of the more enhanced reinforcing effect on the basis of the experiment to which the field characteristic is added.