A high resolution spectrum of PU Vul obtained at Bohyunsan Astronomy Observatory on April 9, 2004 is presented. At this phase, PU Vul was an emission-line star and its continuum was very weak. Emission lines of He II, H I, [Ne IV], [N II], [O III], [Ar V ] and [Fe VII] dominated the spectrum of PU Vul. Many of them exhibited hat-top profiles with strong and multi-peaked emissions on flat-tops of their profiles. Radial velocities for these lines were measured. Origins of the spectral lines are discussed in terms of the wind and the photoionization models.