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온도와 광도가 톨루엔-NOx-공기 혼합물의 광산화 반응에 미치는 영향의 비교
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  • 온도와 광도가 톨루엔-NOx-공기 혼합물의 광산화 반응에 미치는 영향의 비교
저자명
주옥정,배귀남,최지은,이승복,김영성,문길주,윤순창,Ju. Ok-Jung,Bae. Gwi-Nam,Choi. Ji-Eun,Lee. Seung-Bok,Ghim. Young-Sung,Moon. Kil-Choo,Yoon. Soon-Chan
간행물명
한국대기환경학회지
권/호정보
2007년|23권 3호|pp.353-363 (11 pages)
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한국대기환경학회
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

To differentiate temperature effect from the light intensity effect on the formation of secondary products during the photooxidation of toluene-$NO_x$-air mixtures, steady-state air temperature was changed from $20^{circ}C;to;33^{circ}C$ at the same light intensity of $0.39min^{-1}$ in an indoor smog chamber. Smog chamber consisted of 64 blacklights and a $5.8m^3$ reaction bag made of Teflon film. Air temperature was controlled by an air-conditioning system. The starting time for rapid conversion of NO to $NO_2$ was slightly delayed with decreasing air temperature. In contrast to light intensity effect, the ozone formation time and the ozone production rate were insensitive to air temperature. Although the formation time for secondary organic aerosols was not changed, the particle number concentration increased with temperature. However, the newly formed secondary organic aerosol mass at lower temperature was higher than that at higher temperature. Since light intensity significantly affected the starting time and quantity of ozone and aerosol formation, it is considered that the temperature could contribute partly the quantity of aerosol formation during the photooxidation of toluene-$NO_x$-air mixtures.