The present paper deals with the heat/mass transfer characteristics for the rotating impingement/effusion cooling system. By changing the size and number of injection hole, its effects on heat/mass transfer are investigated and three different injection hole cases are considered such as LH, DH and SH, respectively. Reynolds number based on the effusion hole diameter is fixed to 3,330 and two jet orientations are considered. A naphthalene sublimation method is used to obtain the heat/mass transfer coefficients on the effusion plate. The LH case shows that the local heat/mass transfer is significantly varied by the rotation. Moreover, the low and non-uniform Sh distributions occur because the impinging jet is deflected by Coriolis force. Meanwhile, for DH and SH cases, the local heat/mass transfer coefficients are enhanced significantly compared to LH case and the rotation effect decreases with increasing the jet velocity. The averaged Sh value of DH and SH case rises up to 45%, 85% than that of LH case. However, the uniformity of heat/mass transfer deteriorates due to the steep variation of heat/mass transfer.