Performance evaluation of advanced piezoelectric composite actuator is conducted with its application of structural vibration control. Characteristics of MFC(macro fiber composite) actuator are investigated by comparing traditional piezoceramic patch actuator. Finite element modeling is used to obtain equations of motion and boundary effects of smart hull structure with MFC actuator. Dynamic characteristics of the smart hull structure are studied through modal analysis and experimental investigation. LQG control algorithm is employed to investigate active damping of hull structure. It is observed that vibration of hull structure is suppressed effectively by the MFC actuators.