The precipitable water vapors (PWVs) obtained from Global Positioning System (GPS) and Microwave Radiometer (MWR) measurements have been compared for validation of precision of the GPS PWV at Daegwallyoung station for 21 days from Sep. 30 to Oct. 20, 2006. The GPS PWV is estimated using the delay of GPS signals due to the water vapor in the atmosphere with a local mean temperature equation, called HP model, and the MWR PWV by the combinational radiance observation of two channels (23.8 and 31.4 GHz). During the co-observation period, the MWR and GPS PWV show a similar trend, and the bias between the PWVs is 1.7 mm on average. When the bias is removed, the PWV of GPS gives good agreement with that of MWR, having about 1 mm for both the standard deviation and RMS error between the GPS and MWR PWV.