The air quality modeling was carried out to assess the impact of air quality for large scale urban development. The site for the assessment is Multi-fuctional Administrative City which locates in Yeongi-gun, Chungcheongnam-do and estimated population in 2030 is 500,000. Two automatic weather monitoring stations were installed to monitor the meteorological variables for a year and upper air meteorological parameters were measured using radiosonde for 5 days with 4 hours interval in every season. The air quality of standard air pollutants were also measured for 5 days continuously in every season. The results of wind field analysis based on the site measurements and CALMET modeling showed that the valley and mountain winds were prevailed when the sypnotic wind was weak. It also showed that wind speed and directions were highly space-variable within the site basin. The variable wind characteristics implies that the Gaussian dispersion model such ISC3 and AERMOD are not appropriate and the unsteady-sate Lagrangian model such as CALPUFF is preferable. CALPUFF model was applied to assess air quality impact of new sources. The new sources were those for individual and group heating facilities as well as the traffic increases. The results showed that the estimated concentrations of CO and $SO_2$ pollutants by summing the impact concentration of new sources by the dispersion model and the ambient air concentrations by the site measurements were acceptable but those of PM-10 and $NO_2$ would violate ambient air quality standards at several locations due to high ambient air concentrations. It is recommended that the emission reductions near the site should be enforced to improve the ambient air quality.