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Behavior of Oxygen Equilibrium Pressure in CRT Glass Melts doped with Sb and Ce ions from the Viewpoint of Fining
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  • Behavior of Oxygen Equilibrium Pressure in CRT Glass Melts doped with Sb and Ce ions from the Viewpoint of Fining
  • Behavior of Oxygen Equilibrium Pressure in CRT Glass Melts doped with Sb and Ce ions from the Viewpoint of Fining
저자명
Kim. Ki-Dong,Kim. Hyo-Kwang,Kim. Jun-Hong
간행물명
한국세라믹학회지
권/호정보
2007년|44권 8호|pp.419-423 (5 pages)
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한국세라믹학회
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정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The behavior of oxygen gas participating in fining was observed in CRT (Cathode Ray Tube) glass melts doped with $Sb_2O_5;or;CeO_2$ by means of a yttria-stabilized zirconia (YSZ) electrode. The temperature dependence of the oxygen equilibrium pressure ($P_{o2}$) or the activity in both melts showed typical behavior corresponding to a theoretical redox reaction. In other words, the $P_{o2}$ value of melts with $CeO_2$ was lower than that of melts with $Sb_2O_5$ above $1250^{circ}C$. The result implies that $Sb_2O_5$, is more efficient as a fining agent compared to $CeO_2$. On the other hand, melts from a batch containing $Sb_2O_5;and;KNO_3$ showed much higher $P_{o2}$ values compared to melts without $KNO_3$ above $1350^{circ}C$. It is suggested that the addition of $KNO_3$ to CRT glass batch contributes partly to the first fining of the melts.