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초저이온농도에서 이온교환수지에 의한 실리카제거 평형특성
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  • 초저이온농도에서 이온교환수지에 의한 실리카제거 평형특성
저자명
윤태경,이강춘,노병일,Yoon. Tae-Kyung,Lee. Gang-Choon,Noh. Byeong-Il
간행물명
한국환경과학회지
권/호정보
2007년|16권 8호|pp.907-912 (6 pages)
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한국환경과학회
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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Ion exchange resin was used to remove silica ion at ultralow concentration. The effects of temperature, type of ion exchange resin and single/mixed-resin systems on removal efficiency were estimated. As temperature increased, the slope of concentration profile became stiff, and the equilibrium concentration was higher. In the single resin system, the removal of silica was continued up to 400 min, but the silica concentration was recovered to initial concentration after 400 min due to the effect of dissolved $CO_2$. In the mixed-resin system it took about 600 min to reach equilibrium. Because of faster cation exchange reaction than anion exchange reaction, the effect of $CO_2$ could be removed. Based on the experimental results carried out in the mixed-resin system, the selectivity coefficients of silica ion for each ion exchange resin were calculated at some specific temperatures. The temperature dependency of the selectivity coefficient was expressed by the equation of Kraus-Raridon type.