Formation and characteristics of spraying powder for BSCCO High-Tc superconductor prepared by plasma spray coating were investigated. The addition of 3% of binder gives the best flowability of the powder. Ball milling for 30h and 35h gives the best flowability of powder in the case of 2001 and 0212, respectively. The withdraw ratio increases upon binder addition from 12 to 27% in the case of 2001 and from 18 to 31% in the case of 0212 for sieving powder of $30-90{mu}m$ in size. The built-up efficiency for $100{mu}m$ thickness of spray coating is increased more than 30% by binder addition. The microstructure of the spray coated layers was investigated by XRD and EDS analysis.