This paper studies on the wear corrosion behavior of induction hardening high strength cast iron in the acidic environments. In a variety of pH solutions, wear corrosion behavior of GC 300 with a variety of contact pressures was investigated, and corrosion wear behavior after immersion test was considered. Also, electrochemical polarization test for GC 300 was carried out in various pH solutions. The main results are as following: In the strong acidic environment, wear corrosion rate of GC 300 appears highly and in the neutral environment is stable. Also, graphitic corrosion in the strong acidic environment occurs. The corrosion current density of GC 300 becomes high in a order of pH 1 > pH 2 > pH 4 > pH 6.5.