In this study, the mechanisms of binary droplet collision were studied with diesel, ethanol and purified water. The droplet collisions of liquid droplet have been investigated for the same droplet diameter. In order to obtain the digital images of the droplet collision behavior, the experimental equipment was composed of the droplet generating system and the droplet visualization system. The droplets were produced by the vibrating orifice monodisperse generator. The visualization system consisted of a long distance microscope, a light source, and a high speed camera. The outcomes of binary droplet collision can be divided into four regimes, bouncing, coalescence, reflexive separation and stretching separation. The impact angle and the relative velocity of binary droplet are main parameters of collision phenomena, so the transition mechanism of droplet collision can be divided by the impact parameter.