This study evaluated the flexural properties and fire resistance of polyolefm based structural synthetic fiber reinforced concrete. The effects of differing fiber length, dimension and fiber volume fraction were studied. Flexural and fire resistance test were conducted in accordance with the JCI SF-4 and RABT time heating temperature curve, respectively. The Flexural test results indicated that the polyolefln based structural fiber reinforcement showed an ability to increase the flexural toughness and good fire resistance significantly(as compared to steel fiber reinforcement).