This study was conducted to define a characteristics of Electrical Resistivity of weathered soil against volumetric water content and frequency. It is essential to analyze and understand a characteristics of the Electrical Resistivity for evaluation of soil as subsurface contaminant detection. Before the test, an effect of pore water and ion were checked using four liquids(distilled water, tap water, potassium chloride 1.8mM, and 3.7mM). As a result, the correlation between the volumetric water content and the Electrical Resistivity was estimated. The Electrical Resistivity decreases with increasing frequency and water content. Also, Electrical Resistivity could be described by an exponential function of volumetric water content with the constants.