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Influence of Nitrogen/argon Flow Ratio on the Crystallization of Hafnium Oxynitride Films
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  • Influence of Nitrogen/argon Flow Ratio on the Crystallization of Hafnium Oxynitride Films
  • Influence of Nitrogen/argon Flow Ratio on the Crystallization of Hafnium Oxynitride Films
저자명
Choi. Dae-Han,Choi. Jong-In,Park. Hwan-Jin,Chae. Joo-Hyun,Kim. Dae-Il
간행물명
Transactions on electrical and electronic materials
권/호정보
2008년|9권 1호|pp.12-15 (4 pages)
발행정보
한국전기전자재료학회
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정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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Hafnium oxynitride films have been deposited onto a silicon substrate by means of radio frequency (RF) reactive sputtering using a hafnium dioxide $(HfO_2)$ target with a variety of nitrogen! argon $(N_2/Ar)$ gas flow ratios. Auger electron spectroscopy (AES)results confirm that $N_2$ was successfully incorporated into the HfON films. An increase in the $N_2/Ar$ gas flow ratio resulted in metal oxynitride formation. The films prepared with a $N_2/Ar$ flow ratio of 20/20 sccm show (222), (530), and (611) directions of $HfO_2N_2$, and the (-111), (311) directions of $HfO_2$. From X-ray reflectometry measurements, it can be concluded that with $N_2$ incorporated into the HfON films, the film density increases. The density increases from 9.8 to $10.1g/cm^3$. XRR also reveals that the surface roughness is related to the $N_2/Ar$ flow ratio.