Recently, much attention has been paid to the problem such as sick building syndrome, which caused by the indoor air pollutant. Volatile Organic Compounds $(VOC_s)$ and formaldehyde have been considered as one of the main reason that causes indoor air pollutant. This study is for introducing and designing thermal performance of super energy saving building by conducting $VOC_s$ and formaldehyde concentration in the 3Liter house. The results of the measurement for 10 months showed that $VOC_s$ and formaldehyde decreased until the guideline concentration. It took about 7 months, and it appeared right after new construction. However, their levels were showed higher concentration in comparison with the ordinary residential houses (apartment house). The main difference of between newly built 3Liter house and ordinary apartment is their air changes, which are 0.67/h for 3Liter house and 4.0/h for the apartment.